{2-[(1,3-Benzothiazol-2-yl) methoxy]-5-fluorophenyl}(4-chlorophenyl)-methanone

被引:1
|
作者
Venugopala, K. N. [1 ]
Nayak, Susanta K. [2 ]
Govender, Thavendran [1 ]
Kruger, Hendrik G. [3 ]
Maguire, Glenn E. M. [3 ]
机构
[1] Univ KwaZulu Natal, Sch Pharm & Pharmacol, ZA-4000 Durban, South Africa
[2] Univ Rennes 1, UMR 6226, Inst Sci, Equipe Chim Solide & Materiaux, F-35042 Rennes, France
[3] Univ KwaZulu Natal, Sch Chem & Phys, ZA-4000 Durban, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词
D O I
10.1107/S1600536813014621
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C21H13ClFNO2S, contains two independent molecules with similar conformations. In the molecules, the thiazole ring is essentially planar [maximum atomic deviations = 0.014 (4) and 0.023 (5) angstrom] and is oriented with respect to the fluorophenyl ring and chlorophenyl rings at 9.96 (18) and 70.39 (18)degrees in one molecule and at 7.50 (18) and 68.43 (18)degrees in the other; the dihedral angles between the fluorophenyl and chlorophenyl rings are 64.9 (2) and 64.6 (2)degrees, respectively. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot F hydrogen bonds stabilize the three-dimensional supramolecular architecture. Weak C-H center dot center dot center dot pi and pi-pi interactions [centroid-centroid distance = 3.877 (3) angstrom] lead to a criss-cross molecular packing along the c axis.
引用
收藏
页码:O1007 / +
页数:13
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