THE ADDITION OF HALOGENOCARBONS TO ALKENES IN THE PRESENCE OF [FE2(CO)4(ETA-C5H5)2] AND RELATED COMPLEXES

被引：34

作者：

DAVIS, R ^{[1
]}

DURRANT, JLA ^{[1
]}

KHAZAL, NMS ^{[1
]}

BITTERWOLF, TE ^{[1
]}

机构：

[1] USN ACAD,DEPT CHEM,ANNAPOLIS,MD 21402

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85248-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A kinetic study has been made of the addition of halogenocarbons to alkenes in the presence of [Fe2(CO)4(η-C5H5)2] (I). The results, together with the results of cross-over addition reactions of a halogenocarbon mixture and cross-over studies on catalyst mixtures of I and [Fe2(CO)4(η-C5Me5)2] (II) have been interpreted in terms of a mechanism which involves catalysis by an intact dinuclear species, probably [Fe2(CO)3(η-C5R5)2], but which also involves free radical intermediates. © 1990.

引用

页码：229 / 239

页数：11

共 50 条

[1] ADDITION OF HALOGENOCARBONS OR DIHYDROGEN TO ALKENES IN THE PRESENCE OF [FE2(CO)4(ETA-C5H5)2] - CATALYSIS BY A DINUCLEAR SPECIES
DAVIS, R
KHAZAAL, NMS
MAISTRY, V
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (17) : 1387 - 1389
[2] THE REACTION OF [FE2(ETA-C5H5)2(CO)4] WITH ALKYL ISOCYANIDES - [FE2(ETA-C5H5)2(CNME)4] [FE2(ETA-C5H5)2(CNET)4]
MCNALLY, G
MURRAY, PT
MANNING, AR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 243 (04) : C87 - C88
[3] FLUXIONALITY OF FE2(CO)4(ETA-C5H5)2 REVISITED
FARRUGIA, LJ
MUSTOO, L
ORGANOMETALLICS, 1992, 11 (08) : 2941 - 2944
[4] THE ADDITION OF HALOGENOCARBONS TO ALKENES IN THE PRESENCE OF [MO2(CO)4(ETA-C5H5)2], [MO2(CO)4(ETA-C5ME5)], [MO2(CO)6(ETA-C5H5)2] AND [(MO(CO)3(ETA-C5H4))2CH2]
DAVIS, R
KHAZAL, NMS
BITTERWOLF, TE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 397 (01) : 51 - 58
[5] THE REACTIONS OF ACIDS AND ALKYL IODIDES WITH [FE2(ETA-C5H5)2(CNME)4] AND RELATED COMPLEXES
MANNING, AR
MURRAY, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (11): : 2399 - 2404
[6] THE REACTIONS OF AGI ELECTROPHILES WITH [FE2(ETA-C5H5)2(CO)2(CO)(CN(ME)H)(], [FE2(ETA-C5H5)2(CO)2(CNME)(CN(ME)H)] SALTS
CALLAN, B
MANNING, AR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (03) : 325 - 333
[7] THE OXIDATIVE CLEAVAGE OF [FE2(ETA-C5H5)2(CO)4] BY STRONG ACIDS IN ACETONITRILE SOLUTION
CALLAN, B
MANNING, AR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 252 (03) : C81 - C82
[8] SYNTHESIS, STRUCTURE AND DYNAMICS OF [FE2(CN)(ETA-C5H5)2(CO)3]-
FEHLHAMMER, WP
SCHRODER, A
SCHODER, F
FUCHS, J
VOLKL, A
BOYADJIEV, B
SCHROLKAMP, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 411 (03) : 405 - 417
[9] THE ADDITION OF ISONITRILES TO [(MO(CO)2(ETA-C5H5))2], [(W(CO)2(ETA-C5H5))2] - SYNTHESES AND PROPERTIES OF [M2(MU-ETA-2-CNR)(CO)4(ETA-C5H5)2] (M = MO OR W, R = ME OR BUT) AND [(MO(CNME)(CO)2(ETA-C5H5))2], [(MO(CNBUT)(CO)2(ETA-C5H5))2] - X-RAY CRYSTAL-STRUCTURES OF [MO2(MU-ETA-2-CNBUT)(CO)4(ETA-C5H5)2] AND [(MO(CNBUT)(CO)2(ETA-C5H5))2]
ADAMS, H
BAILEY, NA
BANNISTER, C
FAERS, MA
FEDORKO, P
OSBORN, VA
WINTER, MJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (02): : 341 - 348
[10] FORMATION OF [FEM(ETA-C5H5)(CO)4(MU-CO)(MU-CR=CR'H)] (M = FE OR RU) COMPLEXES FROM THE REACTION OF [MH(ETA-C5H5)(CO)2] WITH [FE2(CO)9] AND ACETYLENES - X-RAY STRUCTURE OF [FERU(ETA-C5H5)(CO)4(MU-CO)(MU-CPH=CPHH)]
YANEZ, R
ROS, J
MOLDES, I
MATHIEU, R
SOLANS, X
FONTBARDIA, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (10): : 3147 - 3150

← 1 2 3 4 5 →