THE APPLICATION OF AN ULTRAMICROELECTRODE IN HOMOGENEOUS CATALYTIC REACTION .1. GENERAL CHARACTERISTIC OF A HOMOGENEOUS CATALYTIC REACTION AT AN ULTRAMICROELECTRODE WITH ARBITRARY GEOMETRY UNDER STEADY-STATE

被引：11

作者：

DONG, SJ

CHE, GL

机构：

[1] Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Academia Sinica, Changchun

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 14期

关键词：

ULTRAMICROELECTRODE; STEADY STATE VOLTAMMETRY; HOMOGENEOUS CATALYSIS; ARBITRARY GEOMETRY; GENERAL CHARACTERISTICS;

D O I：

10.1016/0013-4686(92)87056-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A general characteristic of the electrochemical process coupling with a homogeneous catalytic reaction at an ultramicroelectrode under steady state is described. It was found that the electrochemical process coupling with homogeneous catalytic reaction has a similar steady state voltammetric wave at an ultramicroelectrode with arbitrary geometry. A method of determination for the kinetic constant of homogeneous catalytic reaction at an ultramicroelectrode with arbitrary geometry is proposed.

引用

页码：2587 / 2589

页数：3

共 22 条

[1] EVALUATION OF KINETIC-PARAMETERS FROM STEADY-STATE VOLTAMMOGRAMS AT ULTRAMICRODISK ELECTRODES [J].

ABE, T ;

ITAYA, K ;

UCHIDA, I ;

AOKI, K ;

TOKUDA, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (10) :3417-3420

[2]

Amatore C., 1987, J ELECTROANAL CHEM, V220, P49

[3] REVERSIBLE SQUARE-WAVE VOLTAMMOGRAMS INDEPENDENCE OF ELECTRODE GEOMETRY [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H ;

OSTERYOUNG, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 207 (1-2) :25-39

[4] THEORY OF STATIONARY CURRENT POTENTIAL CURVES AT MICRODISK ELECTRODES FOR QUASI-REVERSIBLE AND TOTALLY IRREVERSIBLE ELECTRODE-REACTIONS [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 235 (1-2) :87-96

[5] FAST ELECTRON-TRANSFER RATE FOR THE OXIDATION OF FERROCENE IN ACETONITRILE OR DICHLOROMETHANE AT PLATINUM DISK ULTRAMICROELECTRODES [J].

BOND, AM ;

HENDERSON, TLE ;

MANN, DR ;

MANN, TF ;

THORMANN, W ;

ZOSKI, CG .

ANALYTICAL CHEMISTRY, 1988, 60 (18) :1878-1882

[6] THEORY OF ELECTROCHEMICAL PROCESSES AT AN INLAID DISK MICROELECTRODE UNDER STEADY-STATE CONDITIONS [J].

BOND, AM ;

OLDHAM, KB ;

ZOSKI, CG .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 245 (1-2) :71-104

[7] STEADY-STATE VOLTAMMETRY [J].

BOND, AM ;

OLDHAM, KB ;

ZOSKI, CG .

ANALYTICA CHIMICA ACTA, 1989, 216 (1-2) :177-230

[8] OHMIC POTENTIAL DROP AT ELECTRODES EXHIBITING STEADY-STATE DIFFUSION CURRENTS [J].

BRUCKENSTEIN, S .

ANALYTICAL CHEMISTRY, 1987, 59 (17) :2098-2101

[9] REPRESENTATION OF REVERSIBLE CURRENT FOR ARBITRARY ELECTRODE GEOMETRIES AND ARBITRARY POTENTIAL MODULATION [J].

COPE, DK ;

TALLMAN, DE .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 303 (1-2) :1-15

[10]

DEANAULT G, 1990, J ELECTRONAL CHEM, V280, P243

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