THE 1ST TOTAL SYNTHESIS OF CARMINIC ACID

被引：18

作者：

ALLEVI, P ^{[1
]}

ANASTASIA, M ^{[1
]}

CIUFFREDA, P ^{[1
]}

FIECCHI, A ^{[1
]}

SCALA, A ^{[1
]}

BINGHAM, S ^{[1
]}

MUIR, M ^{[1
]}

TYMAN, J ^{[1
]}

机构：

[1] BRUNEL UNIV,DEPT CHEM,UXBRIDGE UB8 3PN,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 18期

关键词：

D O I：

10.1039/c39910001319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first synthesis of carminic acid (7-beta-D-glucopyranosyl-1-methyl-3,5,6,8-tetrahydroxy-9,10-anthraquinone-2-carboxylic acid), was accomplished by direct C-glucosylation of ethyl 3,5,8,9,10-pentamethoxy-1-methylanthracene-2-carboxylate, here synthesized, which affords ethyl 7-(2,3,4,6-tetra-O-benzyl-beta-D-glucopyranosyl)-3,5,8,9,10- pentamethoxyl-1-methylanthracene-2-carboxylate and carminic acid by regeneration of the masked functionalities.

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页码：1319 / 1320

页数：2

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