MOLTEN LITHIUM CARBONATE-SODIUM CARBONATE-POTASSIUM CARBONATE EUTECTIC - REACTION OF GROUP-VB AND GROUP-VIB METAL-OXIDES AND OXYANIONS

被引：22

作者：

HABBOUSH, DA ^{[1
]}

KERRIDGE, DH ^{[1
]}

TARIQ, SA ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HAMPSHIRE,ENGLAND

来源：

THERMOCHIMICA ACTA | 1979年 / 28卷 / 01期

关键词：

D O I：

10.1016/0040-6031(79)87013-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The reactions of seven acidic oxides and oxyanions of Group VB and VIB metals with molten alkali metal carbonate eutectic have been studied by thermogravimetry. Products have been identified by reflectance, infrared and Raman spectroscopy and stoichiometries have been established for the sequential reactions as oxide anions were progressively incorporated, ultimately to form the ortho-oxyanion. © 1979.

引用

页码：143 / 153

页数：11

共 33 条

[1]

BARKER MG, 1972, INORGANIC CHEM 1, V2, pCH1

[2]

Brough B.J., 1967, INORG CHIM ACTA, V1, P267

[3]

BUSSEY RH, 1964, J CHEM PHYS, V41, P215

[4] SODIUM URANATES - PREPARATION AND THERMOCHEMICAL PROPERTIES [J].

CORDFUNKE, EH ;

LOOPSTRA, BO .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1971, 33 (08) :2427-+

[5] RAMAN STUDIES ON SPECIES IN AQUEOUS SOLUTIONS .3. VANADATES MOLYBDATES AND TUNGSTATES [J].

GRIFFITH, WP ;

LESNIAK, PJB .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (07) :1066-&

[6]

HABBOUSH DA, 1974, THERMOCHIM ACTA, V60, P187

[7] MOLTEN CARBONATE ELECTROLYTES AS ACID-BASE SOLVENT SYSTEMS [J].

JANZ, GJ .

JOURNAL OF CHEMICAL EDUCATION, 1967, 44 (10) :581-&

[8] STRUCTURE OF VANADIUM-POTASSIUM CATALYST DURING OXIDATION OF SULFUR-DIOXIDE AND OXIDATION MECHANISM [J].

KATO, A ;

SEIYAMA, T ;

TOMODA, K ;

MOCHIDA, I .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (03) :690-+

[9]

KATO A, 1970, KYUSHU DAIGAKU KOGAK, V42, P939

[10]

KUZMOVICH VV, 1969, ELEKTROKHIMIYA, V5, P1064

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