SYNTHESIS OF DIARYL DISELENIDES HAVING CHIRAL PYRROLIDINE RINGS WITH C-2 SYMMETRY - THEIR APPLICATION TO THE ASYMMETRIC METHOXYSELENENYLATION OF TRANS-BETA-METHYLSTYRENES

被引：101

作者：

FUJITA, K ^{[1
]}

IWAOKA, M ^{[1
]}

TOMODA, S ^{[1
]}

机构：

[1] UNIV TOKYO, COLL ARTS & SCI, DEPT CHEM, MEGURO KU, TOKYO 153, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 05期

关键词：

D O I：

10.1246/cl.1994.923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active diaryl diselenides carrying C-2 symmetrical chiral pyrrolidines are synthesized by the condensation between 2,2'-diselenobis(benzyl chloride) derivatives and chiral pyrrolidines and are applied to methoxyselenenylation of trans-olefins. The observed diastereomeric excess (d.e.) is up to 60%.

引用

页码：923 / 926

页数：4

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