THE RHODIUM-CATALYZED HYDROBORATION OF OLEFINS - A MECHANISTIC INVESTIGATION

被引：81
作者：
EVANS, DA
FU, GC
机构：
[1] Department of Chemistry, Harvard University, Cambridge
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 08期
关键词：
D O I：
10.1021/jo00295a007
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Labeling studies carried out on the rhodium-catalyzed olefin hydroboration reaction reveal that the degree of reversibility of the elementary steps in the catalytic cycle is highly substrate dependent. The implications of these observations are discussed. © 1990, American Chemical Society. All rights reserved.
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收藏
页码：2280 / 2282
页数：3
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