Phase-transfer catalysis in reactions with the participation of polyvinyl chloride

被引：0

作者：

Leplyanin, GV

Salimgareeva, VN

机构：

[1] Institute of Organic Chemistry, Ufa Scientific Center of Ural Branch of the Russian Academy of Sciences, Ufa, 450054

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 10期

关键词：

phase-transfer catalysis; polyvinyl chloride; polyacetylene; interface; supramolecular structure; dehydrochlorination;

D O I：

10.1007/BF00707201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When polyvinyl chloride is dehydrochlorinated under conditions of phase transfer catalysis, the nature of the interface determines the supramolecular structure of the synthesized polyacetylene, the packing density of crystalline regions in the polyacetylene, and the chemical properties of the polymer. The ionic mechanism of catalysis of these reactions has been established.

引用

页码：1805 / 1814

页数：10

共 40 条

[1]

[Anonymous], PHASE TRANSFER CATAL

[2]

BAGDASARYAN KS, 1972, ENTSIKLOPEDIYA POLIM

[3] MECHANISTIC STUDIES IN STRONGLY BASIC MEDIA .2. INDICATOR EQUILIBRIA IN T-BUTYL ALCOHOL [J].

BETHELL, D ;

COCKERIL.AF .

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1966, (09) :913-&

[4]

BOGUSALVSKII LI, 1975, ELEKTROSINTEZ BIOELE

[5] SYNTHESIS OF A 2-DIMENSIONAL ARRAY OF ORGANIC FUNCTIONAL-GROUPS - SURFACE-SELECTIVE MODIFICATION OF POLY(VINYLIDENE FLUORIDE) [J].

DIAS, AJ ;

MCCARTHY, TJ .

MACROMOLECULES, 1984, 17 (12) :2529-2531

[6]

DIAS AJ, 1983, POLYM MATER SCI ENG, V49, P574

[7]

FAINGOLDMURSHAK V, 1985, POLYM COMMUN, V26, P358

[8] REACTION OF CROSS-LINKED CHLOROMETHYL POLYSTYRENE WITH 1,4-BUTANEDITHIOL - SITE-SITE INTERACTIONS AND THEIR CONTROL [J].

FARRALL, MJ ;

FRECHET, JMJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (25) :7998-7999

[9] CHEMICAL MODIFICATION OF HALOGENATED POLYMERS UNDER PHASE-TRANSFER CONDITIONS [J].

FRECHET, JMJ .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A15 (05) :877-890

[10] APPLICATION OF PHASE-TRANSFER CATALYSIS TO THE CHEMICAL MODIFICATION OF CROSS-LINKED POLYSTYRENE RESINS [J].

FRECHET, JMJ ;

DESMET, MD ;

FARRALL, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (11) :1774-1779

← 1 2 3 4 →