Phase-transfer catalysis in reactions with the participation of polyvinyl chloride

被引：0
作者：
Leplyanin, GV
Salimgareeva, VN
机构：
[1] Institute of Organic Chemistry, Ufa Scientific Center of Ural Branch of the Russian Academy of Sciences, Ufa, 450054
来源：
RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 10期
关键词：
phase-transfer catalysis; polyvinyl chloride; polyacetylene; interface; supramolecular structure; dehydrochlorination;
D O I：
10.1007/BF00707201
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
When polyvinyl chloride is dehydrochlorinated under conditions of phase transfer catalysis, the nature of the interface determines the supramolecular structure of the synthesized polyacetylene, the packing density of crystalline regions in the polyacetylene, and the chemical properties of the polymer. The ionic mechanism of catalysis of these reactions has been established.
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页码：1805 / 1814
页数：10
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