THE CATALYTICALLY ACTIVE CONFORMATION OF CYCLO-[(S)-HIS-(S)-PHE] AS DETERMINED BY SOLID-STATE NWR

被引：16

作者：

APPERLEY, D

NORTH, M

STOKOE, RB

机构：

[1] UNIV COLL N WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

[2] UNIV DURHAM,IND RES LAB,DURHAM DH1 3LE,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 08期

关键词：

D O I：

10.1016/0957-4166(95)00239-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid state conformation of the amorphous catalyst cyclo-[(S)-His-(S)-Phe] is determined by a combination of solid state H-1 and C-13 NMR techniques. The results provide strong evidence in support of the previously proposed mechanism for the asymmetric addition of HCN to aldehydes catalysed hy this dipeptide.

引用

页码：1869 / 1872

页数：4

共 28 条

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