2,3-Bis(4-(3-(trifluoromethyl)-3H-diazirin-3-yl)phenyl)oxirane

被引：1

作者：

Wang, Lei ^{[1
]}

Yoshida, Takuma ^{[1
]}

Okamoto, Masashi ^{[1
]}

Sakihama, Yasuko ^{[1
]}

Hashidoko, Yasuyuki ^{[1
]}

Hashimoto, Makoto ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Agr, Div Appl Biosci, Kita Ku, Kita 9,Nishi 9, Sapporo, Hokkaido 0608589, Japan

来源：

MOLBANK | 2014年 / 01期

关键词：

diazirine; oxirane; photoaffinity label;

D O I：

10.3390/M816

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound, which has two photoreactive groups in a molecule, was synthesized by the coupling reaction of 3-(4-(bromomethyl) phenyl)-3-(trifluoromethyl)-3H-diazirine in the presence of silver oxide in DMSO.

引用

页数：3

共 8 条

[1] A carbene insertion approach to functionalised poly(ethylene oxide)-based gels [J].

Blencowe, Anton ;

Blencowe, Chris ;

Cosstick, Kevin ;

Hayes, Wayne .

REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (04) :868-875

[2]

BRUNNER J, 1980, J BIOL CHEM, V255, P3313

[3] Recent progress in diazirine-based photoaffinity labeling [J].

Hashimoto, Makoto ;

Hatanaka, Yasumaru .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (15) :2513-2523

[4] SIMPLE AND STEREOCONTROLLED PREPARATION OF BENZOYLATED PHENYLALANINE USING FRIEDEL - CRAFTS REACTION IN TRIFLUOROMETHANESULFONIC ACID FOR PHOTOAFFINITY LABELING [J].

Murai, Yuta ;

Wang, Lei ;

Muto, Yasuyuki ;

Sakihama, Yasuko ;

Hashidoko, Yasuyuki ;

Hatanaka, Yasumaru ;

Hashimoto, Makoto .

HETEROCYCLES, 2013, 87 (10) :2119-2126

[5] Simple and versatile method for tagging phenyldiazirine photophores [J].

Nakashima, Hiroyuki ;

Hashimoto, Makoto ;

Sadakane, Yutaka ;

Tomohiro, Takenori ;

Hatanaka, Yasumaru .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15092-15093

[6] Generation of sulfur ylides from sulfonium salts and their reactions. Comparative study of electrochemical reduction with the base method and mechanism elucidation by the MO method [J].

Okazaki, Y ;

Ando, F ;

Koketsu, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (11) :2155-2165

[7] Planar-chiral pyridine n-oxides, a new family of asymmetric catalysts:: Exploiting an η5-C5Ar5 ligand to achieve high enantioselectivity [J].

Tao, B ;

Lo, MMC ;

Fu, GC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (02) :353-354

[8] Convenient one-pot synthesis of trans-1,2-diaryloxiranes from the direct coupling of benzyl halides [J].

Wong, Freeman M. ;

Chan, Yee Man ;

Chen, David X. ;

Wu, Weiming .

TETRAHEDRON LETTERS, 2010, 51 (50) :6649-6650

← 1 →