COMPARATIVE REACTIVITY OF CYCLOPENTADIENE WITH IVB-ELEMENT AND VB-ELEMENT LIGANDS - REACTIONS WITH VB-ELEMENT HALIDES AND TITANIUM TETRACHLORIDE

被引：41
作者：
JUTZI, P
KUHN, M
机构：
[1] Institut für Anorganische Chemie der Universität
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 173卷 / 02期
关键词：
D O I：
10.1016/S0022-328X(00)81291-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactivity of element substituted cyclopentadienes (el = Si, Ge, Sn, As, Sb) is compared by reactions with Vb-element halides and with titaniumtetrachloride. Hereby already known cp-element compounds and new cyclopentadienyl-titaniumtrichlorides with silicon, germanium, tin, arsenic and antimony substituted cp-rings are formed. The 1H-n.m.r. spectra of these complexes are described. The following row of reactivity is found for the investigated element substituted cyclopentadienes: el = AsMe2<SiMe3<GeMe3<SbMe2<SnMe3. © 1979.
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页码：221 / 229
页数：9
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