OPTICAL STUDIES ON THE INTRAMOLECULAR CHARGE-TRANSFER PROPERTIES OF CONJUGATED BRIDGED DONOR - ACCEPTOR SUPERMOLECULES

被引：1

作者：

SARICIFTCI, NS ^{[1
]}

SEGELBACHER, U ^{[1
]}

WEIGAND, B ^{[1
]}

GRUPP, A ^{[1
]}

MEHRING, M ^{[1
]}

GREGORIUS, H ^{[1
]}

MULLEN, K ^{[1
]}

机构：

[1] J GUTENBERG UNIV,INST ORG CHEM,W-6500 MAINZ 1,GERMANY

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91391-M

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Results of optical absorption, emission experiments on conjugated bridged donor - acceptor (push - pull) molecules in different solvents are reported. Solvatochromic properties of the molecules are analysed and deviations are observed from th usual dye behaviour. By increasing the chain length of the conjugated bridge the lowest energy absorption is only slightly effected whereas the next higher energy transition shifts significantly towards lower energies. An unusual bleaching of the lowest energy absorption is observed upon illumination by UV light that recovers on a long time scale under normal conditions.

引用

页码：2399 / 2402

页数：4

共 4 条

[1] VERY LARGE QUADRATIC NONLINEARITIES IN SOLUTION OF 2 PUSH-PULL POLYENE SERIES - EFFECT OF THE CONJUGATION LENGTH AND OF THE END GROUPS
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BLANCHARDDESCE, M
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[2] MEHRING M, 1989, SPRINGER SERIES SOL, V91, P242
[3] REICHARDT C, 1979, ANGEW CHEM, V91, P119
[4] A SERIES OF DONOR-ACCEPTOR MOLECULES OF THE FORM NH2(C6H4)(C=C)N(C6H4)NO2 - UNUSUAL EFFECTS OF VARYING-N
STIEGMAN, AE
MISKOWSKI, VM
PERRY, JW
COULTER, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5884 - 5886

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