TETRACYCLOALKENYL-MESO-TETRAPHENYLPORPHYRINS AS MODELS FOR THE EFFECT OF NONPLANARITY ON THE LIGHT-ABSORPTION PROPERTIES OF PHOTOSYNTHETIC CHROMOPHORES

被引：138

作者：

MEDFORTH, CJ ^{[1
]}

BERBER, MD ^{[1
]}

SMITH, KM ^{[1
]}

SHELNUTT, JA ^{[1
]}

机构：

[1] SANDIA NATL LABS,DIV FUEL SCI,ALBUQUERQUE,NM 87185

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)97453-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

As the size of the cycloalkenyl ring in synthetic C5-C7 tetracycloalkenyl-meso-tetraphenylporphyrins (TCnTPP) is increased the porphyrin core changes from planar to non-planar, showing that porphyrins with well-defined degrees of ruffling can be synthesized for use in systematic studies to determine the effects of non-planarity. © 1990.

引用

页码：3719 / 3722

页数：4

共 13 条

[1]

Abraham R.J., 1988, INTRO NMR SPECTROSCO

[2] INFLUENCES OF PI-PI-COMPLEX FORMATION, DIMERIZATION, AND BINDING TO HEMOGLOBIN ON THE PLANARITY OF NICKEL(II) PORPHYRINS [J].