THERMODYNAMIC BEHAVIOR OF DILUTE SOLUTIONS OF HYDROGEN AND DEUTERIUM IN TITANIUM AND ZIRCONIUM

被引：27

作者：

MCQUILLAN, AD

WALLBANK, AD

机构：

[1] Department of Physical Metallurgy and Science of Materials, University of Birmingham, Birmingham

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 03期

关键词：

D O I：

10.1063/1.1672101

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An investigation has been made of the partial free energy of very dilute solutions of hydrogen and deuterium in the high-temperature, body-centered cubic forms of titanium and zirconium. Anomalous behavior is found which manifests itself as a departure from Sieverts' law. Analysis of the results indicates that there is a strongly marked minimum in the partial enthalpy at hydrogen and deuterium concentrations of about 1 at.% in both metals. This may be associated with a departure from complete randomness in the distribution of interstitial atoms in the solution.

引用

页码：1026 / +

页数：1

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