Effect of Boron Trioxide on Coke's Inner Carbon Solution Loss Reaction

被引:5
作者
Cui, Ping [1 ]
Wang, An-Juan [1 ]
Wang, Zhong-le [1 ]
Wang, Wei-wei [1 ]
机构
[1] Anhui Univ Technol, Sch Chem & Chem Engn, Anhui Key Lab Coal Clean Convers & Utilizat, Maanshan 243002, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
coke; adsorption; trioxide; inner carbon solution loss reaction;
D O I
10.3103/S1068364X13070065
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Boron Trioxide (B2O3) was adsorbed on coke through boric acid (H3BO3) solution, of which the concentration was 0.1%, 0.5%, 1.0%, 2.0% respectively. The existence form and distribution of boron (B) adsorbed on coke were characterized by X-Ray powder diffraction (XRD), X - ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and Inductive coupled plasma (ICP), effect of B2O3 adsorbed on coke was investigated by carbon solution loss reaction (CSLR) under the condition of the same weight loss. Results show that: H3BO3 changes into B2O3 after adsorption treatment, and is adsorbed on coke successfully; B2O3 exhibits negative effect on coke CSLR; with the solution concentration increases, the negative effect is strengthened, and coke's inner reactivity becomes severer, which is not beneficial for coke strength.
引用
收藏
页码:253 / 257
页数:5
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