trans-Chloridobis(ethane-1,2-diamine-kappa N-2,N ')(thiocyanato-kappa N)cobalt(III)diamminetetrakis(thiocyanato-kappa N)-cromate(III)

被引：0

作者：

Rusanova, Julia A. ^{[1
]}

Semenaka, Valentyna V. ^{[1
]}

Zubatyuk, Roman I. ^{[2
]}

机构：

[1] Tams Shevchenko Natl Univ, Dept Inorgan Chem, Volodymyrska Str 64 13, UA-01601 Kiev, Ukraine

[2] Natl Acad Sci Ukraine, Inst Single Crystals, lnst Scintillat Mat, UA-61001 Kharkov, Ukraine

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

Data-to-parameter ratio = 32.2; Mean σ(C-C) = 0.009 Å; R factor = 0.052; Single-crystal X-ray study; T = 293 K; wR factor = 0.141;

D O I：

10.1107/S1600536814003869

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title ionic complex [CoCl(NCS)(C2H8N2)(2)][Cr(NCS)(4)-(NH3)(2)], which crystallizes as a non-merohedral twin, is build up of a complex cation [CoCl(NCS)(en)(2)](+) (en is ethane-1,2-diamine) and the Reinecke's salt anion [Cr(NCS)(4)-(NH3)(2)](-) as complex counter-ion. A network of N-H center dot center dot center dot S and N-H center dot center dot center dot Cl hydrogen bonds, as well as short S center dot center dot center dot S contacts [3.538 (2) and 3.489 (3) angstrom], between the NCS groups of the complex anions link the molecules into a three-dimentional supramolecular network. Intensity statistic indicated twinning by non-merohedry with refined weighs of twin components are 0.5662:0.4338.

引用

页码：M110 / +

页数：10

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