PREPARATION OF LONG ALKYL-SUBSTITUTED OLIGOTHIOPHENES

被引：23

作者：

SATO, M

HIROI, M

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 06期

关键词：

D O I：

10.1246/cl.1994.985

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New hexyl-substituted oligothiophenes (sexi-, novi-, duodeci-, and quindeci-thiophenes) were prepared by a Ni(0)-catalyzed coupling reaction of a 5,5''-dibromo-3,3''-dihexyl-2,2':5',2''-therthiophene. The structures were determined by H-1 NMR spectre, GPC data, and elemental analyses. Their pi-pi* transitions were compared with those of poly(alkylthiophenes).

引用

收藏

页码：985 / 988

页数：4

相关论文

共 11 条

[1] STOICHIOMETRIC CONTROL OF THE SUCCESSIVE GENERATION OF THE RADICAL CATION AND DICATION OF EXTENDED ALPHA-CONJUGATED OLIGOTHIOPHENES - A QUANTITATIVE MODEL FOR DOPED POLYTHIOPHENE [J].

FICHOU, D ;

HOROWITZ, G ;

XU, B ;

GARNIER, F .

SYNTHETIC METALS, 1990, 39 (02) :243-259

[2] REGIOSPECIFICITY AND STRUCTURAL-PROPERTIES OF POLYALKYLTHIOPHENES [J].

GALLAZZI, MC ;

CASTELLANI, L ;

ZERBI, G ;

SOZZANI, P .

SYNTHETIC METALS, 1991, 41 (1-2) :495-498

[3] STRUCTURAL BASIS FOR HIGH CARRIER MOBILITY IN CONJUGATED OLIGOMERS [J].

GARNIER, F ;

HOROWITZ, G ;

PENG, XZ ;

FICHOU, D .

SYNTHETIC METALS, 1991, 45 (02) :163-171

[4] SPECTROSCOPIC STUDIES OF SOLUBLE POLY(3-ALKYLTHIENYLENES) [J].

HOTTA, S ;

RUGHOOPUTH, DDV ;

HEEGER, AJ ;

WUDL, F .

MACROMOLECULES, 1987, 20 (01) :212-215

[5] CONDUCTING POLYMERS FROM DIMETHYL-2,2'-BITHIOPHENES [J].

KRISCHE, B ;

HELLBERG, J ;

LILJA, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (19) :1476-1478

[6] PREPARATION OF ALPHA-QUATERTHIOPHENES, ALPHA-SEXITHIOPHENES AND ALPHA-OCTITHIOPHENES [J].

NAKAYAMA, J ;

KONISHI, T ;

MURABAYASHI, S ;

HOSHINO, M .

HETEROCYCLES, 1987, 26 (07) :1793-1796

[7] SOLUBLE CONDUCTING POLYTHIOPHENES [J].

SATO, M ;

TANAKA, S ;

KAERIYAMA, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (11) :873-874

[8]

SATO M, 1987, MAKROMOL CHEM, V188, P1763

[9] NUCLEAR-MAGNETIC-RESONANCE STUDIES ON ELECTROCHEMICALLY PREPARED POLY(3-DODECYLTHIOPHENE) [J].

SATO, MA ;

MORII, H .

MACROMOLECULES, 1991, 24 (05) :1196-1200

[10] STABILITY OF CONDUCTING POLYTHIOPHENE AND DERIVATIVES [J].

TOURILLON, G ;

GARNIER, F .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (10) :2042-2044