KINETICS OF THE PROCESSES OF CATALYTIC CO OXIDATION

被引：0

作者：

Mryglod, I. M. ^{[1
]}

Bzovska, I. S. ^{[1
]}

机构：

[1] Nat Acad Sci Ukraine, Inst Condensed Matter Phys, 1 Sventsitskyi Str, UA-79011 Lvov, Ukraine

来源：

UKRAINIAN JOURNAL OF PHYSICS | 2008年 / 53卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We have investigated the kinetics of the processes of catalytic CO oxidation. The stationary points of the model are found, and the analysis of their stability in the time evolution of the equations of chemical kinetics is carried out. It is revealed that, at intermediate CO pressures, the system has two stable points, so it is in the bistable state. The condition of the existence of a bifurcation region for the model is analytically found. We have deduced the equation for the critical value of pressure p(CO)(c), at which the first-order phase transition from a reactive state with medium O coverage to an inactive state, where the surface is predominantly covered by CO, is occured. The results obtained are compared with those of the lattice-gas reaction model in the mean-field approximation.

引用

页码：529 / 535

页数：7

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