SYNTHESIS AND REACTIONS OF SOME NEW ORGANOMETALLIC COMPOUNDS - SYNTHESIS OF TRIPHENYLSILYLSULFINYLAMINE

Triphenylsilylsulfinylamine (1) was prepared via the reaction of triphenylsilylamine and thionylchloride. The reaction of (1) with copper and sodium metals gave the corresponding azo, and thioazo-derivatives (2, 3). Also cycloaddition products (4a-c) were prepared through the reaction of (1) with some alkenes under Diels-Alder reaction conditions. The nitrilimine (5) was reacted with (1) to give 1,2,3,5-thiatriazole-1-oxide (6).