MOLECULAR ENGINEERING OF LIQUID-CRYSTALLINE POLYMERS BY LIVING POLYMERIZATION .28. TAILOR MADE LIQUID-CRYSTALLINE NETWORKS EXHIBITING A CHIRAL SMECTIC-C (S-ASTERISK-C) MESOPHASE VIA LIVING CATIONIC COPOLYMERIZATION

被引：6
|
作者：
PERCEC, V
ZHENG, Q
机构：
[1] Department of Macromolecular Science, Case Western Reserve University, Cleveland, 44106, OH
来源：
POLYMER BULLETIN | 1992年 / 29卷 / 05期
关键词：
D O I：
10.1007/BF00296710
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Living cationic copolymerization of (2S, 3S)-(+)-2-chloro-3-methylpentyl 4'-(8-vinyloxyoctyloxy)biphenyl-4-carboxylate (15-8) with 2-vinyloxyethyloxy methacrylate (16-2) leads to reactive copolymers poly[(15-8)-co-(16-2)]X/Y (where X/Y is the mol ratio between the two monomers in the copolymer) containing methacryloyl side groups. The thermally crosslinked copolymers with X/Y=5/5 to 9/1 display an enantiotropic chiral smectic C (S(C)*) mesophase.
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页码：501 / 508
页数：8
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