Crystal structure of beta-D,L-allose

被引：2

作者：

Ishii, Tomohiko ^{[1
]}

Senoo, Tatsuya ^{[1
]}

Kozakai, Taro ^{[2
]}

Fukada, Kazuhiro ^{[2
]}

Sakane, Genta ^{[3
]}

机构：

[1] Kagawa Univ, Dept Adv Mat Sci, Fac Engn, 2217-20 Hayashi Cho, Takamatsu, Kagawa 7610396, Japan

[2] Kagawa Univ, Dept Appl Biol Sci, Fac Agr, Takamatsu, Kagawa 7610795, Japan

[3] Okayama Univ Sci, Dept Chem, Fac Sci, Kita Ku, Okayama 7000005, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; racemic compound; rare sugar; O-H center dot center dot center dot O hydrogen bonding;

D O I：

10.1107/S2056989015000353

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C6H12O6, a C-3 position epimer of glucose, was crystallized from an equimolar mixture of D- and l-allose. It was confirmed that D-allose (l-allose) formed beta-pyranose with a C-4(1) (C-1(4)) conformation in the crystal. In the crystal, molecules are linked by O-H center dot center dot center dot O hydrogen bond, forming a three-dimensional framework. The cell volume of the racemic beta-D,L-allose is 739.36 (3) angstrom(3), which is about 10 angstrom(3) smaller than that of chiral beta-D-allose [V = 751.0 (2) angstrom(3)].

引用

页码：O139 / U630

页数：8

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