CONFORMATIONAL DIFFERENCES IN DIOXOURANIUM(VI) COORDINATION-COMPOUNDS - CRYSTAL-STRUCTURE OF THE CHLOROFORM ADDUCT OF N,N'-BIS-SALICYLIDENE-1,5-DIAMINO-3-OXAPENTANE-DIOXOURANIUM(VI)

被引：11

作者：

BOMBIERI, G ^{[1
]}

FORSELLINI, E ^{[1
]}

BENETOLLO, F ^{[1
]}

FENTON, DE ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 10期

关键词：

D O I：

10.1016/0022-1902(79)80207-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound (UO2-saloden·CHCl3) crystallizes in an orthorhombic system, space group Cmc21 with a = 16.938(6), b = 12.440(5) and c = 10.662(4) A ̊, Z = 4. The coordination geometry of the uranium atom is bipyramidal pentagonal with the ligand pentadentate in the equatorial plane of the uranyl ion. The chloroform molecule does not interact directly with the ligand. The IR spectral data are also discussed. © 1979.

引用

页码：1437 / 1441

页数：5

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