QUANTITATIVE AND STRUCTURAL INVESTIGATIONS OF HYDROGEN-BONDING INTERACTIONS IN ANION-BINDING OF MONO-SUBSTITUTED AND 1,1'-BIS-SUBSTITUTED ARYL COBALTOCENIURN RECEPTORS

被引：45

作者：

BEER, PD ^{[1
]}

DREW, MGB ^{[1
]}

GRAYDON, AR ^{[1
]}

SMITH, DK ^{[1
]}

STOKES, SE ^{[1
]}

机构：

[1] UNIV READING, DEPT CHEM, READING RG6 2AD, BERKS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 03期

关键词：

D O I：

10.1039/dt9950000403

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New acyclic monosubstituted aryl cobaltocenium derivatives, functionalised with additional hydrogen-bonding amine groups have been prepared. Quantitative investigation of the anion-binding properties by H-1 NMR spectroscopy and electrochemical methods shows enhanced binding believed to be due to amine group participation in hydrogen bonding. Similar recognition studies on 1,1'-bissubstituted aryl cobaltocenium analogues indicate an order of magnitude selectivity for the dihydrogenphosphate anion over simple halide anions. The importance of hydrogen bonding is also illustrated by the first single-crystal structure showing the anion complex of a cobaltocenium receptor.

引用

页码：403 / 408

页数：6

共 23 条

[1] SELECTIVE ELECTROCHEMICAL RECOGNITION OF THE DIHYDROGEN PHOSPHATE ANION IN THE PRESENCE OF HYDROGEN SULFATE AND CHLORIDE-IONS BY NEW NEUTRAL FERROCENE ANION RECEPTORS [J].

BEER, PD ;

CHEN, Z ;

GOULDEN, AJ ;

GRAYDON, A ;

STOKES, SE ;

WEAR, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (24) :1834-1836

[2] ANION RECOGNITION BY ACYCLIC REDOX-RESPONSIVE AMIDE-LINKED COBALTOCENIUM RECEPTORS [J].

BEER, PD ;

HAZLEWOOD, C ;

HESEK, D ;

HODACOVA, J ;

STOKES, SE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (08) :1327-1332

[3] ANION RECOGNITION BY NEW ACYCLIC QUATERNARY POLYBIPYRIDINIUM RECEPTORS [J].

BEER, PD ;

WHEELER, JW ;

GRIEVE, A ;

MOORE, C ;

WEAR, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1225-1227

[4] MACROCYCLES CONTAINING TIN - PREPARATION OF MACROBICYCLIC LEWIS ACIDIC HOSTS CONTAINING 2 TIN ATOMS AND SN-119 NMR-STUDIES OF THEIR CHLORIDE AND BROMIDE BINDING-PROPERTIES IN SOLUTION [J].

BLANDA, MT ;

HORNER, JH ;

NEWCOMB, M .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (19) :4626-4636

[5] DESIGN OF ANION RECEPTORS - APPLICATIONS [J].

DIETRICH, B .

PURE AND APPLIED CHEMISTRY, 1993, 65 (07) :1457-1464

[6]

Dietrich B., 1984, INCLUSION COMPOUNDS, V2, P337

[7] MULTIPLE MOLECULAR RECOGNITION AND CATALYSIS - A MULTIFUNCTIONAL ANION RECEPTOR BEARING AN ANION BINDING-SITE, AN INTERCALATING GROUP, AND A CATALYTIC SITE FOR NUCLEOTIDE BINDING AND HYDROLYSIS [J].

HOSSEINI, MW ;

BLACKER, AJ ;

LEHN, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (10) :3896-3904

[8] EQNMR - A COMPUTER-PROGRAM FOR THE CALCULATION OF STABILITY-CONSTANTS FROM NUCLEAR-MAGNETIC-RESONANCE CHEMICAL-SHIFT DATA [J].

HYNES, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (02) :311-312

[9] EVALUATION OF SINGLE-CRYSTAL X-RAY-DIFFRACTION DATA FROM A POSITION-SENSITIVE DETECTOR [J].

KABSCH, W .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1988, 21 (06) :916-924

[10] 1,8-NAPHTHALENEDLYLBIS(DICHLOROBORANE) CHLORIDE - THE 1ST BIS-BORON CHLORIDE CHELATE [J].

KATZ, HE .

ORGANOMETALLICS, 1987, 6 (05) :1134-1136

← 1 2 3 →