11,12-SECO-12,13-DIDEHYDROMULTIFLORINE PERCHLORATE HYDRATE

被引：4

作者：

DUTKIEWICZ, G ^{[1
]}

KUBICKI, M ^{[1
]}

BOROWIAK, T ^{[1
]}

WYSOCKA, W ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV POZNAN,FAC CHEM,STEREOCHEM LAB,PL-60780 POZNAN,POLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194011650

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of 11,12-seco-12,13-didehydromultiflorine perchlorate hydrate [IUPAC name: 3-(but-3-enyl)-10-oxo-1,2,3,4,5,6,11, 11a-octahydro-10H-1,5-methanopyrido[1,2-a][1 ,5]diazocinium perchlorate hydrate], C15H23N2O+.ClO4-.H2O, a new alkaloid found in lupin plants, has been confirmed by X-ray analysis. The cation is formed by protonation of the butenyl-bonded N atom, N16. There is significant conjugation in the N1-C2=C3-C4=O4 fragment of the cation. The structure is partially disordered and the molecular packing is governed by a network of intermolecular hydrogen bonds.

引用

页码：1182 / 1184

页数：3

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