N-23 AND C-13 SOLID-STATE NMR-SPECTROSCOPY OF N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE-SODIUMCYCLOPENTADIENIDE

被引：8

作者：

PIETRASS, T ^{[1
]}

BURKERT, PK ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR,W-8046 GARCHING,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 207卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)90717-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The static Na-23 NMR spectrum of N,N,N',N'-tetramethylethylenediamine-sodiumcyclopentadienide revealed a lineshape that could not be unambiguously discussed. Nutation NMR spectroscopy combined with MAS allowed a definite assignment of the splitted signal to a second order quadrupolar interaction with vanishing asymmetry parameter. The quadrupole coupling constant is in the range of 2 MHz. The C-13 CP-MAS spectrum yielded the expected signals.

引用

页码：253 / 254

页数：2

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