ELECTRODE PROCESS IN THE PRESENCE OF A SURFACE-ACTIVE SUBSTANCE WITH ACCELERATING-INHIBITING PROPERTIES

被引：10
作者：
DUTKIEWICZ, E
PUACZ, A
机构：
[1] Department of Electrochemistry, Institute of Chemistry, A. Mickiewicz University, 60-780 Poznań
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 100卷 / 1-2期
关键词：
D O I：
10.1016/S0022-0728(79)80212-0
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The electrode process in the presence of a surface active substance with accelerating-inhibiting properties is considered. The rate constant of the process kσ is expressed as a sum of the rate corresponding to the electrostatic effect kσ1 and that corresponding to the blocking effect kθ; kσ=kσ+kθ. The relations derived describe the experimental data for electroreduction of cadmium ions from a 3 M H2SO4 solution in the presence of benzenesulfonate ions. © 1979 Elsevier Sequoia S.A.
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页码：947 / 956
页数：10
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