MOLECULAR-STRUCTURE OF TRICHLORO(ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM(IV)

被引：38

作者：

MARTIN, A ^{[1
]}

MENA, M ^{[1
]}

PALACIOS, F ^{[1
]}

机构：

[1] UNIV ALCALA DE HENARES, DEPT QUIM INORGAN, CAMPUS UNIV, E-28871 ALCALA DE HENARES, SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 480卷 / 1-2期

关键词：

ZIRCONIUM; DINUCLEAR; X-RAY DIFFRACTION; EARLY TRANSITION METALS; GROUP-4;

D O I：

10.1016/0022-328X(94)87131-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray analysis of the yellow, air-unstable, crystalline compound Cp*ZrCl3 (1) which results from the reaction of ZrCl4 with Cp*SiMe3 confirms the presence of two Cp*ZrCl3 moieties related by a centre of symmetry with two chlorine atoms bridging the metals. 1 is therefore a dimer, despite the molecular structure of [CpZrCl3], which was found to be a polymer.

引用

页码：C10 / C11

页数：2

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