MOLECULAR-STRUCTURE OF TRICHLORO(ETA(5)-PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM(IV)

被引：38
作者：
MARTIN, A [1 ]
MENA, M [1 ]
PALACIOS, F [1 ]
机构：
[1] UNIV ALCALA DE HENARES, DEPT QUIM INORGAN, CAMPUS UNIV, E-28871 ALCALA DE HENARES, SPAIN
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 480卷 / 1-2期
关键词：
ZIRCONIUM; DINUCLEAR; X-RAY DIFFRACTION; EARLY TRANSITION METALS; GROUP-4;
D O I：
10.1016/0022-328X(94)87131-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
X-ray analysis of the yellow, air-unstable, crystalline compound Cp*ZrCl3 (1) which results from the reaction of ZrCl4 with Cp*SiMe3 confirms the presence of two Cp*ZrCl3 moieties related by a centre of symmetry with two chlorine atoms bridging the metals. 1 is therefore a dimer, despite the molecular structure of [CpZrCl3], which was found to be a polymer.
引用
收藏
页码：C10 / C11
页数：2
相关论文
共 50 条
  • [21] Crystal Structure and DFT Calculations of Bis(tetrahydridoborato)bis(cyclopentadienyl)zirconium(IV)
    Lopez, Nayeli G.
    Carter, Carly C.
    Rocha, Sergio
    Thomas, Christina J.
    Falcon, Kevin
    Robledo, Joanna
    Cundari, Thomas R.
    Yousufuddin, Muhammed
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2022, 52 (04) : 434 - 439
  • [22] A physicochemical study of the structure of inorganic electron and ion exchanger based on zirconium(IV), molybdenum(VI), and silicon(IV)
    Bondarenko, T. S.
    Boichinova, E. S.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2006, 79 (09) : 1413 - 1418
  • [23] A physicochemical study of the structure of inorganic electron and ion exchanger based on zirconium(IV), molybdenum(VI), and silicon(IV)
    T. S. Bondarenko
    E. S. Boichinova
    Russian Journal of Applied Chemistry, 2006, 79 : 1413 - 1418
  • [24] Dicyclopentadienyl titanium and zirconium complexes with the double bridged bis(dimethylsilanodiyl) dicyclopentadienyl [(Me(2)Si)(2)(eta(5)-C5H3)(2)](2-) ligand: X-ray molecular structure of [Ti{(SiMe(2))(2)(eta(5)-C5H3)(2)}Me(2)]
    Cano, A
    Cuenca, T
    GomezSal, P
    Manzanero, A
    Royo, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 526 (02) : 227 - 235
  • [25] Molecular structure of hafnium and zirconium acetylacetonates M(C5H7O2)4
    Ezhov, YS
    Komarov, SA
    Sevast'yanov, VG
    JOURNAL OF STRUCTURAL CHEMISTRY, 1998, 39 (01) : 36 - 43
  • [26] Molecular structure of hafnium and zirconium acetylacetonates M(C5H7O2)4
    Yu. S. Ezhov
    S. A. Komarov
    V. G. Sevast’yanov
    Journal of Structural Chemistry, 1998, 39 : 36 - 43
  • [27] CRYSTAL AND MOLECULAR-STRUCTURE OF POLY(ARYL ETHER ETHER DIKETONE)
    PETRACCONE, V
    PIROZZI, B
    CORRADINI, P
    GIUNCHI, G
    POLYMER, 1991, 32 (03) : 396 - 401
  • [28] SYNTHESIS AND MOLECULAR-STRUCTURE OF BIS-(3-DIMETHYLAMINOPROPYLALANE)
    DUMICHEN, U
    THIELE, KH
    GELBRICH, T
    SIELER, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 495 (1-2) : 71 - 75
  • [29] Synthesis, structure, spectroscopic properties, and electrochemical behavior of mixed ligand bis(β-ketoesterato)zirconium (IV) and -hafnium (IV) phthalocyaninates
    Tomachynski, Larisa A.
    Chernii, Victor Ya.
    Kolotilova, Yulia Yu.
    Chernega, Alexander N.
    Howard, Judith A. K.
    Volkov, Sergey V.
    INORGANICA CHIMICA ACTA, 2007, 360 (05) : 1493 - 1501
  • [30] Di- and triphospha-ferrocenes: Crystal and molecular structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(3)(t)Bu(3)P(2))] and of the adducts [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Mo(CO)(5)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))W(CO)(5)]
    Muller, C
    Bartsch, R
    Fischer, A
    Jones, PG
    Schmutzler, R
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 512 (1-2) : 141 - 148
12345