PHENYLSELENOACETALDEHYDE, A USEFUL REAGENT FOR THE HOMOLOGATIVE CONVERSION OF HALIDES TO PHENYLSELENOMETHYL KETONES

被引：60

作者：

BAUDAT, R

PETRZILKA, M

机构：

[1] Départment de Chimie Organique, Université de Genève, Genève, CH-1211, quai Ernest Ansermet

来源：

HELVETICA CHIMICA ACTA | 1979年 / 62卷 / 05期

关键词：

D O I：

10.1002/hlca.19790620505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conversion of primary, secondary and vinylic halides to the two C‐atoms homologated phenylselenomethyl ketones 8 is described. The method involves addition of the readily available phenylselenoacetaldehyde 5 to the Grignard reagents 9 and oxidation of the resulting β‐hydroxy‐selenides 10 Scheme 3. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

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页码：1406 / 1410

页数：5

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