[2,6-Difluoro-3-(pyridin-2-yl-kappa N)pyridin-4-yl-kappa C-4](pentane-2,4-dionato-kappa(2) O,O')iridium( III)

被引：0
|
作者：
Luo, Kaijun [1 ]
Zhang, Chenyang [1 ]
Jia, Juan [1 ]
Luo, Daibing [2 ]
机构：
[1] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Sichuan, Peoples R China
[2] Sichuan Univ, Analyt & Testing Ctr, Chengdu 610065, Sichuan, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1107/S1600536813026160
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound,[Ir(C10H5F2N2)(2)(C5H7O2)], has a distorted octahedral coordination geometry around the Ir III atom, retaining the cis- C, C/trans-N, N chelate disposition in two 2,6-difluoro-3-(pyridin- 2-yl-kappa N) pyridin-4-yl ligands which are nearly mutually perpendicular [dihedral angle = 82.75 (15)degrees]. The molecular structure is stabilized by weak C-H center dot center dot center dot O and C-center dot center dot center dot HF hydrogen- bond interactions. The crystal structure is stabilized by pi-pi stacking interactions (centroid-centroid distance = 3.951 angstrom).
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页码：M590 / +
页数：9
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