CRYSTAL AND MOLECULAR-STRUCTURE OF A TETRAHYDROFURAN CLATHRATE OF THE HEXAMORPHOLINOCYCLOTRIPHOSPHO-NITRILIUM PERCHLORATE

被引：0
作者：
JAUD, J
SCHEIDECKER, S
GRAFFEUIL, M
LABARRE, JF
机构：
[1] UNIV TOULOUSE 3,CNRS,STRUCT & VIE LAB,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE
[2] CTR ELABORAT MAT & ETUD STRUCT,CNRS,29 RUE JEANNE MARVIG,F-31055 TOULOUSE,FRANCE
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 295卷
关键词：
D O I：
10.1016/0022-2860(93)85014-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Complexation in tetrahydrofuran/methyl alcohol (1:1) of copper with hexamorpholinocyclotriphosphazene, N3P3(NC4H8O)6, as the ligand gives a tetrahydrofuran clathrate of hexamorpholinocyclotriphosphonitrilium perchlorate as the major product. The X-ray structure of this serendipitous protonated moiety is provided together with an explanation for its existence.
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页码：133 / 141
页数：9
相关论文
共 19 条
[1]   CRYSTAL AND MOLECULAR-STRUCTURE OF THE 2 MACRO-ANSA AND MACRO-SPIRO ISOMERIC CYCLOTRIPHOSPHAZENES N3P3CL4[HN-(CH2)3-O-(CH2)4-O-(CH2)3-NH] [J].
CAMERON, TS ;
LINDEN, A ;
ELBAKILI, A ;
CASTERA, P ;
FAUCHER, JP ;
GRAFFEUIL, M ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1989, 212 :281-293
[2]   CRYSTAL AND MOLECULAR-STRUCTURE OF THE MEGA-SPIRO CYCLOPHOSPHAZENIC SPECIES FROM DIETHYLENE GLYCOL BIS-(3-AMINOPROPYL)-ETHER, N3P3CL4((HN-(CH2)3-O-(CH2)2-O-(CH2)2-O-(CH2)3-NH)) [J].
CAMERON, TS ;
LINDEN, A ;
SOURNIES, F ;
ELBAKILI, A ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1989, 197 :41-51
[3]  
Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV
[4]   AN ANSWER TO THE SPIRO VERSUS ANSA DILEMMA IN CYCLOPHOSPHAZENES .11. THE 1ST MACRO-SPIRO AND MACRO-ANSA SPECIES FROM DIOXODIAMINES [J].
ELBAKILI, A ;
CASTERA, P ;
FAUCHER, JP ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1989, 195 :21-31
[5]   CRYSTAL AND MOLECULAR-STRUCTURE OF THE TETRAMORPHOLINO DERIVATIVE OF THE CYCLOPHOSPHAZENIC SPIRO (3O2O3)ASTERISK SPECIES, A RADIOPAQUES PRECURSOR [J].
ENJALBERT, R ;
GALY, J ;
SCHEIDECKER, S ;
SEMENZIN, D ;
BONNET, JP ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1992, 269 (3-4) :355-365
[6]   CRYSTAL AND MOLECULAR-STRUCTURE OF THE 1ST MACRO-ANSA AND MACRO-SPIRO ISOMERIC CYCLOPHOSPHAZENES N3P3CL4(HN-(CH2)3-O-(CH2)2-O-(CH2)3-NH) [J].
ENJALBERT, R ;
GALY, J ;
ELBAKILI, A ;
CASTERA, P ;
FAUCHER, JP ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1989, 196 :207-220
[7]   CRYSTAL AND MOLECULAR-STRUCTURE OF THE MONOBINO DICYCLOPHOSPHAZENE N3P3CL5 [HN-(CH2)3-O-(CH2)6-O-(CH2)3-NH] CL5P3N3 [J].
ENJALBERT, R ;
GALY, J ;
ZANIN, B ;
BONNET, JP ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1991, 246 (1-2) :123-131
[8]  
ENJALBERT R, 1990, J MOL STRUCT, V221, P53
[9]   CRYSTAL AND MOLECULAR-STRUCTURE OF A NEW ALLOTROPIC VARIETY OF THE MEGA-SPIRO CYCLOPHOSPHAZENE FROM DIETHYLENE GLYCOL BIS-(3-AMINOPROPYL)-ETHER, N3P3CL4[HN-(CH2)3-O-(CH2)2-O-(CH2)2-O-(CH2)3-NH)] [J].
JAUD, J ;
SOURNIES, F ;
LABARRE, JF .
JOURNAL OF MOLECULAR STRUCTURE, 1989, 212 :305-314
[10]  
JOHNSON CK, 1976, ONRL5138 REP
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