MEASUREMENT OF PRODUCT BRANCHING RATIOS OF THE NCO+NO REACTION

被引：81

作者：

COOPER, WF ^{[1
]}

HERSHBERGER, JF ^{[1
]}

机构：

[1] N DAKOTA STATE UNIV,DEPT CHEM,FARGO,ND 58105

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 02期

关键词：

D O I：

10.1021/j100181a046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction NCO + NO --> products was studied at room temperature using pulsed laser photolysis with time-resolved infrared diode laser detection. CO2, CO, and N2O reaction products were detected by infrared absorption under quantum-state relaxed conditions to provide absolute number densities of each species. The results indicate that three product channels are active: CO2 + N2 is the most important channel, with CO + N2 + O and N2O + CO also contributing significantly.

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页码：771 / 775

页数：5

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