ANOMALOUS IONS IN THE CHEMICAL IONIZATION MASS-SPECTRA OF AROMATIC NITRO AND NITROSO-COMPOUNDS

被引：43
作者：
BROPHY, JJ
DIAKIW, V
GOLDSACK, RJ
NELSON, D
SHANNON, JS
机构：
[1] School of Chemistry, University of New South Wales, Kensington, New South Wales, 2033
来源：
ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 04期
关键词：
D O I：
10.1002/oms.1210140408
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The appearance of [MH‐30]+ ions in the chemical ionization mass spectra of aromatic nitro compounds may be due to their initial reduction to the corresponding amines within the ion source. Aromatic nitroso compounds may be similarly reduced to yield [MH‐14]+ ions. The hydroxy derivatives of the nitroso compounds yield further anomalous ions at [MH‐16]+ probably due to the reduction of the hydroxy groups. Copyright © 1979 John Wiley & Sons, Ltd.
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页码：201 / 203
页数：3
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