OXIDATION OF ACETONE UNDER BAEYER-VILLIGER CONDITIONS - EVIDENCE FOR FORMATION OF ACETONE CARBONYL OXIDE OR ITS ISOMERIC DIOXIRANE

被引：31

作者：

MURRAY, RW

RAMACHANDRAN, V

机构：

[1] Department of Chemistry, University of Missouri — St. Louis, St Louis, Missouri

来源：

PHOTOCHEMISTRY AND PHOTOBIOLOGY | 1979年 / 30卷 / 01期

关键词：

D O I：

10.1111/j.1751-1097.1979.tb07134.x

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Abstract— Oxidation of acetone under Baeyer‐Villager conditions produces a new species which is capable of epoxidizing olefins. It is suggested that this intermediate is acetone carbonyl oxide or its isomer dimethyldioxirane. Copyright © 1979, Wiley Blackwell. All rights reserved

引用

页码：187 / 189

页数：3

共 11 条

[1]

EDWARDS JO, PHOTOCHEM PHOTOBIOL

[2] MECHANISMS OF GAS-PHASE AND LIQUID-PHASE OZONOLYSIS [J].