CHEMOSELECTIVE CARBON-CARBON BOND FORMATION REACTIONS OF ZIRCONACYCLOPENTENES

被引：59

作者：

KASAI, K

KOTORA, M

SUZUKI, N

TAKAHASHI, T

机构：

[1] INST MOLEC SCI,COORDINAT CHEM LABS,OKAZAKI,AICHI 444,JAPAN

[2] GRAD UNIV ADV STUDIES,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 01期

关键词：

D O I：

10.1039/c39950000109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of zirconacyclopentenes with allyl chloride in the presence of a copper salt and a lithium or magnesium salt proceeds at the alkenyl carbon on zirconium with high chemoselectivity; selective C-C bond formation at the alkyl carbon was also achieved by treatment of zirconacyclopentenes with a copper salt and a lithium or magnesium salt, methanol and allyl chloride.

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页码：109 / 110

页数：2

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