PHOTOCHEMISTRY OF CONJUGATED TRIENES - VITAMIN-D REVISITED

被引：38
作者：
JACOBS, HJC
机构：
[1] Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, NL-2300 RA Leiden
来源：
PURE AND APPLIED CHEMISTRY | 1995年 / 67卷 / 01期
关键词：
D O I：
10.1351/pac199567010063
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A survey is given of various factors and conditions that affect the photoreactivity and photoproduct distribution of conjugated trienes, such as ground-state rotameric equilibrium, non-planarity of the chromophore, wavelength of irradiation, solvent and temperature. The effect of changes in ground-state conformation and geometry, caused by substitution or variation of solvent or temperature, usually appears to be more important and more easily predictable than excited state effects.
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页码：63 / 70
页数：8
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