THERMOELECTRIC-POWER OF ALKALI DOPED C-60

被引:7
作者
SUGIHARA, K
INABE, T
MARUYAMA, Y
ACHIBA, Y
机构
[1] TOKYO METROPOLITAN UNIV, DEPT CHEM, TOKYO 19203, JAPAN
[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN
关键词
FULLERENES; ALKALI-DOPED C-60; THERMOELECTRIC POWER;
D O I
10.1143/JPSJ.62.2757
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Thermoelectric power of M3C60 (M=K, Rb) exhibits nearly T-linear dependence with negative sign above the superconducting transition temperature. Small but clear deviation from the linear relation at low temperatures is ascribed to the phonon drag effect. Observed broad dip over approximately 100 K and its small magnitude suggest that the anomaly is not related to the electron-intramolecular phonon interaction but to the electron-intermolecular phonon interaction. The electron-phonon coupling constant D and the phonon velocity are estimated to be approximately 10(-1) eV and several km/sec, respectively. The small value for D is expected from the low Fermi energy obtained from the band calculation and the diffusion thermoelectric power.
引用
收藏
页码:2757 / 2761
页数:5
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