CIRCULAR DICHROISM STUDIES .I. A QUADRANT RULE FOR OPTICALLY ACTIVE AROMATIC CHROMOPHORE IN RIGID POLYCYCLIC SYSTEMS

被引：123

作者：

DEANGELIS, GG

WILDMAN, WC

机构：

[1] Department of Chemistry, Iowa State University of Science and Technology, Ames

来源：

TETRAHEDRON | 1969年 / 25卷 / 20期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4020(01)83255-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The CD spectra of a number of rigid aromatic compounds containing an asymmetric center adjacent to the aromatic ring are reported. From the CD spectra of compounds of known absolute configuration it has been possible to devise a quadrant rule which predicts the absolute configuration of molecules possessing an asymmetric center adjacent to the aromatic ring. The rule has been tested with representative members of the indole, Amaryllidaceae, morphine, and isoquinoline type alkaloids of known absolute configuration. © 1969.

引用

页码：5099 / +

页数：1

共 45 条

[1] OPTICAL ROTATORY DISPERSION .14. BISBENZYLTETRAHYDROISOQUINOLINE ALKALOIDS [J].