INTERPRETATION OF MAGNETIC PROPERTIES OF PFEIFFERS CATION, CR4(OH)6(EN)66+

被引：16
作者：
FLOOD, MT
BARRACLO.CG
GRAY, HB
机构：
[1] Arthur Amos Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena
来源：
INORGANIC CHEMISTRY | 1969年 / 8卷 / 09期
关键词：
D O I：
10.1021/ic50079a009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Magnetic susceptibility data for [Cr4(OH)6(en)6] (N3)6-4H2O are reported from 300 to 4.2°K. The observed antiferromagnetic behavior is satisfactorily accounted for on the basis of the Heisenberg-Dirac-Van Vleck spin-spin coupling model derived from a rhomboid arrangement of the four interacting chromium(III) atoms. © 1969, American Chemical Society. All rights reserved.
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页码：1855 / &
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