THE SYNTHESIS OF BINUCLEATING POLYAZA MACROCYCLIC AND MACROBICYCLIC LIGANDS AND THE DIOXYGEN AFFINITIES OF THEIR COBALT COMPLEXES

被引：21
作者：
CHEN, D
MOTEKAITIS, RJ
MURASE, I
MARTELL, AE
机构：
[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843
[2] DOJINDO LABS,KUMAMOTO 86123,JAPAN
来源：
TETRAHEDRON | 1995年 / 51卷 / 01期
关键词：
D O I：
10.1016/0040-4020(94)00965-W
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of a new macrobicyclic (cryptand) ligand 1,4,9,12,19,20,25,30-octaazabicyclo(10.10.10)dotriacontane, C4BISTREN and improved syntheses of the ligands 7,9,30-trioxa-1,4,10,13,16,22,-27,33-octaazabicyclo(11.11.11)pentatriacontane, OBISTREN and 1,13-dioxa-4,7,10,16,19,22-hexaazacyclotetracosane, OBISDIEN. The Co(II) complexes of these ligands are oxygen carriers. among the six macrocyclic and six macrobicyclic ligands that are considered in this paper, the binuclear cobalt(II) complexes of OBISTREN and OBISDIEN form the most stable dioxygen complexes.
引用
收藏
页码：77 / 88
页数：12
相关论文
共 17 条
[1]  
Busch D. H., 1988, OXYGEN COMPLEXES OXY, P61
[2]  
CALDERAZZO F, 1966, INORG NUCL CHEM LETT, V2, P379
[3]   THE OXYGEN-CARRYING SYNTHETIC CHELATE COMPOUNDS .1. [J].
CALVIN, M ;
BAILES, RH ;
WILMARTH, WK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (11) :2254-2256
[4]   DIOXYGEN AFFINITIES OF SYNTHETIC COBALT SCHIFF-BASE COMPLEXES [J].
CHEN, D ;
MARTELL, AE .
INORGANIC CHEMISTRY, 1987, 26 (07) :1026-1030
[5]   THE SYNTHESIS OF NEW BINUCLEATING POLYAZA MACROCYCLIC AND MACROBICYCLIC LIGANDS - DIOXYGEN AFFINITIES OF THE COBALT COMPLEXES [J].
CHEN, D ;
MARTELL, AE .
TETRAHEDRON, 1991, 47 (34) :6895-6902
[6]   DINUCLEAR COPPER(II) CRYPTATES OF MACROCYCLIC LIGANDS - SYNTHESIS, CRYSTAL-STRUCTURE, AND MAGNETIC-PROPERTIES - MECHANISM OF THE EXCHANGE INTERACTION THROUGH BRIDGING AZIDO LIGANDS [J].
COMARMOND, J ;
PLUMERE, P ;
LEHN, JM ;
AGNUS, Y ;
LOUIS, R ;
WEISS, R ;
KAHN, O ;
MORGENSTERNBADARAU, I .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (23) :6330-6340
[7]   MONOMERIC OXYGEN ADDUCTS OF N,N'-ETHYLENEBIS(ACETYLACETONIMINATO)LIGANDCOBALT(II) . PREPARATION AND PROPERTIES [J].
CRUMBLISS, AL ;
BASOLO, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (01) :55-+
[8]   SYNTHESIS OF MACROBICYCLIC POLYAMINES BY DIRECT MACROBICYCLIZATION VIA TRIPODE-TRIPODE COUPLING [J].
DIETRICH, B ;
HOSSEINI, MW ;
LEHN, JM ;
SESSIONS, RB .
HELVETICA CHIMICA ACTA, 1985, 68 (02) :289-299
[9]   OXYGEN ADDUCTS OF SCHIFFS BASE COMPLEXES OF COBALT PREPARED IN SOLUTION [J].
FLORIANI, C ;
CALDERAZZO, F .
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (06) :946-+
[10]  
FURMAN HH, 1939, SCOTTS STANDARDS MET, V2, P2180
12