A NEW SYNTHESIS OF NITRILES FROM N-METHOXY IMIDOYL BROMIDES BY PHOTOLYSIS

被引：10

作者：

KIKUGAWA, Y ^{[1
]}

FU, LH ^{[1
]}

SAKAMOTO, T ^{[1
]}

机构：

[1] YANBIAN MED COLL,DEPT PHARM,YANJI,JILIN,PEOPLES R CHINA

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 08期

关键词：

D O I：

10.1080/00397919308018582

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NS-Methoxy imidoyl bromides are synthesized in one-pot from the carboxylic acids with methoxyamine and triphenylphosphine-tetrabromo-methane. Photolysis of them leads to formation of the corresponding nitriles in high yield without affecting functional groups sensitive to ordinary dehydrating and halogenating reagents.

引用

页码：1061 / 1069

页数：9

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