VANADIUM(III) OXYCHLORIDE - MAGNETIC, OPTICAL AND ELECTRICAL-PROPERTIES - LITHIUM AND MOLECULAR INTERCALATIONS

被引：20
作者：
VENIEN, JP
PALVADEAU, P
SCHLEICH, D
ROUXEL, J
机构：
[1] (Laboratoire de Chimie des Solides, associé au CNRS (L.A. 279) Faculté des Sciences, F. 44072 Nantes Cédex
来源：
MATERIALS RESEARCH BULLETIN | 1979年 / 14卷 / 07期
关键词：
D O I：
10.1016/0025-5408(79)90154-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Single crystals of vanadium oxychloride have been prepared by reaction between VCl3 and V2O3. An antiferromagnetic behaviour is observed (TN = 150 ± 5 K). Optical and electrical measurements have shown VOCl to be a semi-conductor (∼ 2 eV). The resistivity at room temperature is 5.107Ωcm. Lithium can be intercalated electrochemically or through the butyllithium technique. A definite compound Li0.80VOCl was characterized. Pyridine leads to similar intercalates as in FeOCl. © 1979.
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页码：891 / 897
页数：7
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