COPPER CATALYZED OXIDATION OF SB(3) BY PEROXYDISULFATE

被引：10
作者：
BHARGAVA, AP
GUPTA, YK
GUPTA, KS
机构：
[1] Department of Chemistry, University of Rajasthan, Jaipur
来源：
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 03期
关键词：
D O I：
10.1016/0022-1902(69)80025-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The copper catalyzed oxidation of antimonyl tartrate by peroxydisulfate has been studied in perchloric acid medium and the rate laws in the presence and absence of added tartrate ion determined. A chain mechanism has been suggested and the inhibiting action of Mn(II) and of allyl acetate has been explained by the termination of the chains. The rate of the completely inhibited reaction is comparable to that of the decomposition of the peroxydisulfate. © 1969.
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页码：777 / &
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