DECOMPOSITION KINETICS OF THE N-BROMOAMINOACIDS, N-BROMOALANINE, N-BROMO-2-AMINOBUTYRIC ACID, AND N-BROMONORVALINE

被引：5

作者：

ANTELO, JM ^{[1
]}

ARCE, F ^{[1
]}

CRUGEIRAS, J ^{[1
]}

ARMESTO, JL ^{[1
]}

机构：

[1] UNIV LA CORUNA,FAC CIENCIAS,LA CORUNA,SPAIN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1993年 / 25卷 / 12期

关键词：

D O I：

10.1002/kin.550251203

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic study of the decomposition reactions of N-bromoalanine, N-bromo-2-aminobutyric acid, and N-bromonorvaline shows them to be first-order with respect to N-bromoaminoacid concentration and independent of both excess aminoacid and pH over the interval pH 9-11. In this pH range the mean rate constants at 298 K were 1.20 x 10(-3) s-1, 1.37 x 10(-3) s-1 and 1.28 x 10(-3) s-1, respectively. (C) 1993 John Wiley & Sons, Inc.

引用

页码：995 / 1004

页数：10

共 25 条

[1] Dielectric constants of some organic solvent-water mixtures at various temperatures [J].