Novel Green Hydrogel Material using Bacterial Cellulose

The green bacterial cellulose (BC)-based hydrogel materials have successfully prepared by modification and crosslink BC. BC was derived from acetic acid bacteria isolated and selected from ripe fruits. The production of BC was performed by fermentation in various media. It was found that using liquid potato medium represented the highest thickness of BC film (0.80 cm) with 2 wt% solid content covered the media. To reduce the crystallization of BC, carboxyl group was introduced into BC chains using a carboxymethylation reaction giving carboxymethyl BC (CMBC) and subsequently crosslinked with divinyl sulfone (DVS). The extent of crosslinking influenced on the swelling properties of the hydrogels. Using large DVS amounts (>30 wt%-of CMBC), dense macromolecular network with less capacity spaces in the hydrogel was formed. The maximum water retention value of green hydrogels containing similar to 3.0 mmol carboxyl groups/g CMBC reached 27 (g/g).