SELECTIVE HYDROGENATION OF FATS AND DERIVATES USING ZIEGLER-TYPE ORGANOMETALLIC CATALYSTS III - SELECTIVE HYDROGENATION OF SATURATED AND UNSATURATED FATTY-ACID NITRILES TO SATURATED AND UNSATURATED PRIMARY AND SECUNDARY AMINES

被引：6
作者：
FELL, B
SOJKA, J
机构：
来源：
FETT WISSENSCHAFT TECHNOLOGIE-FAT SCIENCE TECHNOLOGY | 1991年 / 93卷 / 03期
关键词：
D O I：
10.1002/lipi.19910930301
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A tallow oil nitrile fraction with 66% oleonitrile and 27% stearonitrile was hydrogenated under use of homogeneous nickel- or cobalt-metallorganic catalysts from Ziegler-type with high selectivity to the corresponding saturated primary and secondary amines or under conservation of the double bond in the oleonitrile to unsaturated primary or secondary fatty amines. The realized selectivities were: 97% for stearylamine, 100% for oleylamine, 97% for distearylamine and 76% for dioleylamine.
引用
收藏
页码：79 / 90
页数：12
相关论文
共 52 条
[1]  
BAYER E, 1986, J CHEM SOC CHEM COMM, V12, P949
[2]   CATALYTIC ACTIVITY OF POLYNUCLEAR PLATINUM CARBONYL ANIONS IN HOMOGENEOUS HYDROGENATION REACTIONS [J].
BHADURI, S ;
SHARMA, KR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (04) :727-732
[3]   SELECTIVE REDUCTIONS .26. LITHIUM TRIETHYLBOROHYDRIDE AS AN EXCEPTIONALLY POWERFUL AND SELECTIVE REDUCING AGENT IN ORGANIC-SYNTHESIS - EXPLORATION OF THE REACTIONS WITH SELECTED ORGANIC-COMPOUNDS CONTAINING REPRESENTATIVE FUNCTIONAL-GROUPS [J].
BROWN, HC ;
KIM, SC ;
KRISHNAMURTHY, S .
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (01) :1-12
[4]  
Dewhirst K.C., 1969, U.S. Patent, Patent No. [3,454,644, 3454644]
[5]  
DEWHIRST KC, 1969, Patent No. 3480659
[6]  
DEWHIRST KC, 1970, Patent No. 3489786
[7]  
DURAND D, 1981, Patent No. 4271323
[8]  
DURAND D, 1974, Patent No. 2421934
[9]   DETERMINATION OF NITRILES WITH LITHIUM ALUMINUM-HYDRIDE [J].
EGLI, RA ;
MULLER, H .
FRESENIUS ZEITSCHRIFT FUR ANALYTISCHE CHEMIE, 1972, 259 (01) :23-&
[10]  
GAILLARD J, 1975, Patent No. 2236840
123456