LASER-INDUCED FLUORESCENCE OF SE2 AND TE2 IN RARE-GAS MATRICES

被引：36

作者：

BONDYBEY, VE

ENGLISH, JH

机构：

来源：

JOURNAL OF CHEMICAL PHYSICS | 1980年 / 72卷 / 12期

关键词：

D O I：

10.1063/1.439149

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The laser induced fluorescence excitation and resolved emission spectra of Se2 and Te2 suggest that these species are only insignificantly perturbed by the solid medium. The spectroscopy of both molecules in the matrix is governed by efficient nonradiative transitions among numerous low lying electronic states and fast vibrational relaxation. Several new electronic states of these species are observed and characterized. © 1980 American Institute of Physics.

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页码：6479 / 6484

页数：6

相关论文

共 19 条

[1]

AHMED F, 1979, 34TH S MOL SPECTR CO

[2] RAMAN SPECTRUM OF S2 [J].

BARLETTA, RE ;

CLAASSEN, HH ;

MCBETH, RL .

JOURNAL OF CHEMICAL PHYSICS, 1971, 55 (11) :5409-&

[3] B(3SIGMAU-)-X(3SIGMAG-) BAND SYSTEM OF SE2 MOLECULE [J].

BARROW, RF ;

CHANDLER, GG ;

MEYER, CB .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1966, 260 (1113) :395-&

[4] TRIPLET SPLITTING IN GROUND STATE, X3SIGMA-G, OF S2 [J].

BARROW, RF ;

KETTERING, JM .

CANADIAN JOURNAL OF PHYSICS, 1963, 41 (02) :419-&

[5]

BARROW RF, 1972, P ROY SOC LOND A MAT, V237, P279

[6] B3SIGMAU-PRE-DISSOCIATION AND RELAXATION PROCESSES IN MATRIX ISOLATED-S2 [J].

BONDYBEY, VE ;

ENGLISH, JH .

JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (05) :3113-3122

[7] S2-FLUORESCENCE AND EXCITATION-SPECTRA IN SOLID AR [J].

BONDYBEY, VE ;

ENGLISH, JH .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (05) :1865-1868

[8] ULTRAVIOLET FLUORESCENT AND ABSORPTION SPECTRA OF S2 ISOLATED IN INERT-GAS MATRICES [J].

BREWER, L ;

BRABSON, GD .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (09) :3274-&

[9] UV ABSORPTION SPECTRUM OF TRAPPED S2 [J].

BREWER, L ;

BRADSON, GD ;

MEYER, B .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (04) :1385-&

[10]

FOURNIER J, 1977, J CHEM PHYS, V66