AN INVESTIGATION OF THE THERMAL-DECOMPOSITION OF POLY(3-NITRATOMETHYL-3-METHYLOXETANE)

被引：12

作者：

BUNYAN, PF

机构：

[1] Defence Research Agency, Royal Armament Research and Development Establishment, Sevenoaks, Kent TN14 7BP, Fort Halstead

来源：

THERMOCHIMICA ACTA | 1992年 / 207卷

关键词：

D O I：

10.1016/0040-6031(92)80131-F

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The decomposition of poly(3-nitratomethyl-3-methyloxetane) (polyNIMMO) was studied using the techniques of differential calorimetry, thermogravimetry, heat flow calorimetry and adiabatic calorimetry. In all cases the decomposition appears to follow an Arrhenius temperature dependence relationship and a single non-autocatalytic first-order rate law throughout the reaction. This contrasts with the autocatalytic decomposition behaviour of traditional nitrate ester propellant ingredients, at present in service use.

引用

页码：147 / 159

页数：13

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