THE 1ST STRUCTURALLY CHARACTERIZED HOMOLEPTIC THORIUM ALKOXIDE - X-RAY CRYSTAL-STRUCTURE OF [TH(OCH(PR-ISO)2)4]2, AND NMR EVIDENCE FOR A MONOMER DIMER EQUILIBRIUM

被引：20

作者：

CLARK, DL ^{[1
]}

HUFFMAN, JC ^{[1
]}

WATKIN, JG ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000266

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and X-ray crystal structure of the dimeric five-coordinate homoleptic thorium alkoxide [Th(OCHPr(i)2)4]2, the first X-ray structural characterisation of a homoleptic thorium alkoxide complex, are reported: H-1 NMR findings evidence an equilibrium between the dimer [Th(OCHPr(i)2)4]2 and its monomer [Th(OCHPr(i)2)4].

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页码：266 / 268

页数：3

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