MEDIUM EFFECTS IN UNSYMMETRICAL DISULFIDES COMPOUNDS SYNTHESIS FROM BUNTE SALTS

被引：28
|
作者：
HIVER, P
DICKO, A
PAQUER, D
机构：
[1] Laboratoire de Chimie Organique, Université de Metz, 57045 Metz, Ile du Saulcy
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 51期
关键词：
D O I：
10.1016/0040-4039(94)88513-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The present study allows us to show the influence of the polarity of the reaction, medium as well as the electron-donating and withdrawing character of para substituents of alpha-halogeno tuluenes in the preparation of unsymmetrical disulfides using the Bunte salt method. The use of DMSO as a reaction solvent permits not only to dissociate the sodium salt, but also to synthesise unsymmetrical disulfides from compounds, which are inadequate using conventional methods.
引用
收藏
页码：9569 / 9572
页数：4
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